某型柴油机排烟温度异常故障排查与分析

针对某油船主推进柴油机排烟温度异常升高的故障,从引起柴油机排烟温度异常升高的可能因素着手进行排查.结果表明:排烟波纹管内衬套开裂脱落,堵塞排烟管是导致排烟温度异常升高的直接原因.指出:案例中的这个因素虽比较少见,但还是有迹可循;可为船舶柴油机的使用管理与维修实践提供一定借鉴.     

Investigation of Ce0.9Gd0.1O2-δ dispersed Sm1.5Sr0.5NiO4+δ: Cathode for intermediate temperature solid oxide fuel cell applications

Dispersion of nanocrystalline (94–350 nm) Ce_0.9Gd_0.1O_2-δ in superfine (260–312 nm) Sm_1.5Sr_0.5NiO_4+δ using modified precipitation technique is established using X-ray powder diffraction, scanning electron microscopy and transmission electron microscopy. Presence of Ce_0.9Gd_0.1O_2-δ grains inhibits grain growth of Sm_1.5Sr_0.5NiO_4+δ, which provides morphological stability (up to 1100 °C). Ce_0.9Gd_0.1O_2-δ concentration dependent behaviours of ionic conductivity, surface exchange rate and electrode polarization resistance (R_p) of composites (determined using electrochemical impedance spectroscopy) are comprehended using percolation model. Three oxygen reduction reaction mechanisms are considered to understand electrochemical performance. Minimum R_p (0.81 Ω cm² at 700 °C) for 70Sm_1.5Sr_0.5NiO_4+δ:30Ce_0.9Gd_0.1O_2-δ is correlated to percolation threshold (optimum (i) electrochemically active sites (ii) oxygen reduction reaction kinetics, (iii) O^2- conductivity and (iv) charge transfer rate). Nano crystallite size of Ce_0.9Gd_0.1O_2-δ is crucial for enhancement in electrochemical performance. Oxygen partial pressure dependent electrochemical impedance spectroscopy studies reveal dominance of coexisting non-charge transfer oxygen adsorption/desorption and bulk O^2- diffusion.     

EFPI-FBG复合光纤传感器高温大应变试验研究

由于缺乏航空发动机/燃气轮机服役环境下叶片温度、应变有效性检测的技术与装置，所以工作叶片的温度环境、载荷环境和应变分布等关键数据的缺失是故障检修工作中的最大困难之一。采用非本征型法布里-珀罗(Extrinsic Farby Perot Interferometric,EFPI)与光纤光栅(Fiber Bragg Grating,FBG)传感技术，研制了一种基于单模光纤的EFPI FBG复合光纤传感器及其解调设备。通过搭建高温拉伸试验平台，开展了基于DZ125材料试件的复合光纤传感器高温、大应变测量的性能测试。试验结果表明：复合光纤传感器的工作温度范围为26 ℃~1 100 ℃，温度测量精度不超过全量程的5%，分辨率为0.066 ℃；F-P传感器的应变测量范围为0~19 468 με，在1 100 ℃下的相对误差为1.96%，分辨率为0.053 με。     

The effects of warmth and CO2 concentration,with and without bioeffluents,on the emission of CO2 by occupants and physiological responses

The emission rate of carbon dioxide (CO₂) depends on many factors but mainly on the activity level (metabolic rate) of occupants. In this study, we examined two other factors that may influence the CO₂ emission rate, namely the background CO₂ concentration and the indoor temperature. Six male volunteers sat one by one in a 1.7 m³ chamber for 2.5 h and performed light office-type work under five different conditions with two temperature levels (23 vs. 28°C) and three background concentrations of CO₂ (800 vs. 1400 vs. 3000 ppm). Background CO₂ levels were increased either by dosing CO₂ from a cylinder or by reducing the outdoor air supply rate. Physiological responses to warmth, added CO₂, and bioeffluents were monitored. The rate of CO₂ emission was estimated using a mass-balance equation. The results indicate a higher CO₂ emission rate at the higher temperature, at which the subjects were warm, and a lower emission rate in all conditions in which the background CO₂ concentration increased. Physiological measurements partially explained the present results but more measurements are needed.     

Microstructure characterization and compressive performance of 3D needle-punched C/C–SiC composites fabricated by gaseous silicon infiltration

3D needle-punched C/C-SiC composites were fabricated from carbon fiber reinforced carbon (C/C) preforms, with densities of 1.05?g/cm³ and 1.28?g/cm³, by the gaseous silicon infiltration (GSI) method at fabrication temperatures from 1500?°C to 1800?°C. The compressive strengths and elastic moduli in transverse direction are larger than those measured under longitudinal compression except that samples fabricated from 1.28?g/cm³ density exhibit lower elastic moduli in transverse direction than in longitudinal direction. The compressive strength and modulus increase with fabrication temperature at 1500?°C and 1600?°C, and then decrease with higher fabrication temperature. Samples fabricated from the lower density C/C preforms have greater compressive strength and modulus. X-ray tomography was applied before and after the mechanical tests to characterize the microstructure and damage patterns, and the results indicated that for C/C-SiC composites fabricated at 1700?°C from 1.28?g/cm³ density C/C preform the matrix has a volume fraction (vol%) of 36.9%, and the initial intra-bundle cracks (0.6?vol%) display a space crossing structure while the inter-bundle pores (6.0?vol%) are special irregularly distributed.     

Synthetic copolymer (AM/AMPS/DMDAAC/SSS) as rheology modifier and fluid loss additive at HTHP for water-based drilling fluids

In the petroleum industry, high temperature and high pressure (HTHP) would dramatically worsen rheological properties and increase fluid loss volumes of drilling fluids. Synthetic polymer as an indispensable additive has attracted more and more attention recently. In this article, a new copolymer (named AADS) of 2-acrylamide-2-methylpropanesulfonic acid, acrylamide, dimethyl diallyl ammonium chloride, and sodium styrene sulfonate was synthesized through aqueous solution polymerization. The chemical structure of the copolymer was characterized by Fourier transform infrared spectroscopy and nuclear magnetic resonance. Moreover, its thermal stability was simultaneously analyzed using a differential scanning calorimetry. The results showed that the synthetic polymer contained all the designed functional groups, and its structure was consistent to the desired one. Under contamination of sodium chloride, AADS solution maintained relatively high viscosity in high concentration brine, showing a good antisalt capacity. Furthermore, the effect of AADS content and temperature on rheological behavior and fluid loss volume of the water-based drilling fluid (WBDF) containing the synthesized product were investigated according to the American Petroleum Institute standard. Results showed that the rheological and filtration properties of the prepared WBDF were improved with the increase in the AADS concentration before and after the thermal aging test. In addition, in the temperature range of 80–240 °C, a reversible rheological behavior was observed during the heating–cooling process, and the HTHP fluid loss was controlled within 22.5 mL, suggesting that the copolymer AADS was suitable for making WBDF s with high temperature resistance. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47813.     

1 GWt PB-FHR负荷跟踪运行特性分析

为研究熔盐堆系统在商业应用中的价值，分析其是否满足电网负荷的变化需求和安全运行的能力，本文以1 GWt球床式氟盐冷却高温堆（PB-FHR）为研究对象，仿真计算其在负荷跟踪模式下的瞬态行为和运行特性。以RELAP5/MOD4.0程序为研究工具，并植入相关的熔盐物性与计算关系式，建立氟盐冷却高温堆的热工水力系统与功率控制系统的仿真模型，对典型负荷工况参数变化情况下控制系统的响应特性进行仿真分析。结果表明：该氟盐冷却高温堆系统在设计的控制逻辑的调控下，展示出良好的负荷跟踪运行能力，堆芯功率能迅速响应负荷变化，功率超调和温度超调小，反应堆的运行参数始终处于合理的运行范围内。     

碱度对包钢高炉渣物理性能的影响

摘要：为探明二元碱度对包钢高炉渣物理性能的影响机理，基于包钢7号高炉渣化学组成，添加纯试剂CaO、SiO2调整炉渣的二元碱度。通过实验研究二元碱度对包钢7号高炉渣熔化温度、黏度和熔化性温度的影响规律；同时采用Factsage70热力学软件，计算了不同碱度下炉渣的液相线温度和热焓值。结果表明：随着碱度升高，炉渣熔化温度不断升高，黏度和熔化性温度先降低后升高，碱度在1.1～1.3之间，碱度每提高0.1，炉渣半球温度提高4.67℃，软熔区间为3.33～4.60℃；碱度在1.1～1.4之间，1450℃以上炉渣黏度均低于0.5Pa·s，流动性良好；Factsage7.0计算结果表明：随着碱度的升高，炉渣的液相线温度不断升高，热焓值不断降低。综合考虑碱度对包钢炉渣熔化温度、熔化性温度、热焓和黏度的影响规律，建议包钢高炉渣的碱度应控制在1.1～1.3之间。     

PS-PVD热障涂层抗沙尘冲刷行为研究

为提高PS-PVD热障涂层的抗沙尘冲刷性能,采用等离子喷涂-物理气相沉积技术(PS-PVD)在粘结层表面制备7YSZ热障涂层,在大气环境下进行了抗沙尘冲刷试验,研究了PS-PVD热障涂层的冲刷行为及失效机制。通过等离子喷涂技术(APS)在PS-PVD热障涂层表面制备了一层致密层状涂层,重点研究了致密层厚度对PSPVD热障涂层抗冲刷失效性能的影响。结果表明PS-PVD热障涂层冲刷过程经历了快速、中速、慢速冲刷三个阶段。随着致密层厚度的增加,对PS-PVD热障涂层抗冲刷性能的提升愈加明显。当致密层厚度为5μm时,对PS-PVD热障涂层抗冲刷性能无明显影响;当致密层厚度为10μm时,PS-PVD热障涂层抗冲刷性能提高了约30%;当致密层厚度为20μm时,PS-PVD热障涂层抗冲刷性能约提高了4倍。     

High-Tg porous polyimide films with low dielectric constant derived from spiro-(adamantane-2,9′(2′,7′-diamino)-fluorene)

Porous polyimide (PI) films with low dielectric constants and excellent thermal properties have been a pressing demand for the next generation of high-performance, miniature, and ultrathin microelectronic devices. A series of novel porous PI films containing fluorenyl-adamantane groups were prepared successfully via thermolysis of poly(ethylene glycol) (PEG) added in the PI matrix. The cross-sectional morphologies of porous PI films showed closed pores with diameters ranging from 135 to 158 nm, which were uniform and regular in shape without interconnectivity. These porous PI films exhibited excellent thermal properties with a glass-transition temperature at 376 °C whereas the 5% weight loss temperature in air excess of 405 °C due to enhanced rigidity afforded by fluorenyl-adamantane groups. Accompanied by thermolysis content of PEG increasing from 0 to 20 wt %, the density of porous PI films decreased, and the corresponding porosity grew significantly from 0 to 11.48%. Depending on porosity, the dielectric constant and dielectric loss of porous PI films significantly declined from 2.89 to 2.37 and from 0.050 to 0.021, respectively. These excellent properties benefit the as-prepared porous PI films for application as interlayer dielectrics, integrated circuit chips, or multichip modules in microelectronic fields. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47313.